By M. Harmata
The advance and alertness of cycloaddition technique is still on the vanguard of analysis in man made natural chemistry. This quantity starts with a evaluate of equipment to be had for the synthesis of 7-membered jewelry and is with paintings on metal-catalyzed cycloadditions. there's then an replace at the cycloaddition chemistry of 2-pyrone, after which a special program of photocycloaddition is particular. the ultimate bankruptcy is a dialogue of the most recent explorations of the response of rhodium-stabilized vinyl carbenoids with dienes.
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Additional info for Advances in Cycloaddition. Volume 5
65. ; Breuer, E. J. Am. Chem. Soc. 1959, 6522-6523. 66. Pasto, D. ; Chen, A. J. Am. Chem. Soc. 1973,95, 1553. Pasto, D. ; Chen, A. E-T. Tetrahedron Lett. 1973, 713. , unpublished results. 67. Fowler, E W. Angew. , Int. Ed. Engl. 1971, 10, 135. 68. ; Ugi, I. Angew. , Int. Ed. Engl. 1985, 24, 594. 69. ; Lanzendorfer, E J. Am. Chem. Soc. 1984, 106, 373. Baldwin, J. ; Pinschmidt, R. , Jr. Tetrahedron Lett. 1971, 935. 70. ; Podszun, W. Angew. , Int. Ed. Engl. 1969, 8, 976. " Sarel, S. Tetrahedron Lett.
48 48 [4+2] Cycloadditions of 2-Pyrones with Alkynes . . . . [4+2] Cycloadditions of 2-Pyrones with Alkenes . . . . A. Aromatic Products . . . . . . . . . . . B. D i h y d r o b e n z e n e Products . . . . . . . . . C. D o u b l e D i e l s - A l d e r Cycloadditions . . . . . . D. Isolable Bicycloadducts . . . . . . . . . . Conclusions . . . . . . . . . . . . . . Acknowledgments . . . . . . . . . .
Murray, C. ; Yang, D. C. J. Am. Chem. Soc. 1990, 112, 3642. 38. Davies, H. M. ; Matasi, J. ; Hodges, L. ; Huby, N. J. ; Houser, J. H. J. Org. Chem. 1997, 62, 1095. 39. Griesbeck, A. G. J. Prakt. Chem. 1993, 335, 489. 40. Wender, P. ; Eissenstat, M. ; Filosa, M. P. J. Am. Chem. Soc. 1979, 101, 2196. 41. Davies, H. M. ; Doan, B. D. J. Org. Chem. 1998, 63, 657. For additional examples of the scope of this reaction, see Davies, H. M. ; Matasi, J. ; Hodges, L. ; Huby, N. J. ; Houser, J. H. J. Org.
Advances in Cycloaddition. Volume 5 by M. Harmata