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By Thomas B. Drew

ISBN-10: 0120085054

ISBN-13: 9780120085057

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Pergamon, New York, 1957. P6. Penner, S. , and Jacobs, T. , Ann. Rev. Phys. Chem. 11, 391 (1960). P7. Penner, S. , and Mullins, B. ” Pergamon, New York, 1959. 36 P8. P9. P10. P11. J. F. WEHNER Penner, S. , and Williams, F. , Astronaut. Acla 7 , 171 (1961). , A. , Progr. Combust. Sci. Technol. I, 145 (1960). , Fuel 28, 25 (1949). , and Avery, W. , J. Chem. Phys. 22, 145 (1954). R1. , Symp. Combust. 7th London Ozjord, 1968 p. 339 (1959). Butterworths, London. 81. , and Sevmtyanova, I. , Combust.

They also depend upon the particular initial condition chosen. Since it is now possible to integrate the flame equations for more general models than the single-reaction flame, it appears feasible to develop a more general theory of ignition by extending the techniques of reference (Yl). In particular, it would be interesting to investigate the energy requirements for the generation of the steady-state profile of intermediate species. D. TRANSITION TO DETONATION The laminar combustion wave, which is often characterized by the term deflagration, is only one possible mode through which a metastable reaction mixture may be transformed into a set of thermodynamically stable products.

One should distinguish carefully the difference between ignition and flame stabilization. Practical ignition must involve ignition in the region of a flame holder and thus includes stabilization. It would appear that the minimum energy requirement in this case would be related to the establishment of the steady-state profile. I n the case of the ignition of a traveling flame, some part of the energy necessary to establish the steady-state profile may be accumulated FLAME PROCESSES-HEORETICAL AND EXPERIMENTAL 21 during the nonsteady period, The minimum ignition energy in this ease is just sufficient to balance the heat losses so that chemical reaction can accelerate.

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Advances in Chemical Engineering by Thomas B. Drew

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