By Thomas B. Drew
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Pergamon, New York, 1957. P6. Penner, S. , and Jacobs, T. , Ann. Rev. Phys. Chem. 11, 391 (1960). P7. Penner, S. , and Mullins, B. ” Pergamon, New York, 1959. 36 P8. P9. P10. P11. J. F. WEHNER Penner, S. , and Williams, F. , Astronaut. Acla 7 , 171 (1961). , A. , Progr. Combust. Sci. Technol. I, 145 (1960). , Fuel 28, 25 (1949). , and Avery, W. , J. Chem. Phys. 22, 145 (1954). R1. , Symp. Combust. 7th London Ozjord, 1968 p. 339 (1959). Butterworths, London. 81. , and Sevmtyanova, I. , Combust.
They also depend upon the particular initial condition chosen. Since it is now possible to integrate the flame equations for more general models than the single-reaction flame, it appears feasible to develop a more general theory of ignition by extending the techniques of reference (Yl). In particular, it would be interesting to investigate the energy requirements for the generation of the steady-state profile of intermediate species. D. TRANSITION TO DETONATION The laminar combustion wave, which is often characterized by the term deflagration, is only one possible mode through which a metastable reaction mixture may be transformed into a set of thermodynamically stable products.
One should distinguish carefully the difference between ignition and flame stabilization. Practical ignition must involve ignition in the region of a flame holder and thus includes stabilization. It would appear that the minimum energy requirement in this case would be related to the establishment of the steady-state profile. I n the case of the ignition of a traveling flame, some part of the energy necessary to establish the steady-state profile may be accumulated FLAME PROCESSES-HEORETICAL AND EXPERIMENTAL 21 during the nonsteady period, The minimum ignition energy in this ease is just sufficient to balance the heat losses so that chemical reaction can accelerate.
Advances in Chemical Engineering by Thomas B. Drew